A crown-shaped 24-molybdate cluster constructed by organotriphosphonate ligand.
نویسندگان
چکیده
A crown-shaped organic-inorganic hybrid polyoxomolybdate, Na5[H7{N(CH2PO3)3}Mo6O16(OH) (H2O)4]4·18H2O (1) has been presented and characterized. Such an intriguing structure consists of a 24-molybdenum-membered polyanion constructed by organotriphosphonate ligands, which represents the highest nuclearity of metal atoms in the area of organophosphonate-based polyoxometalates.
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ورودعنوان ژورنال:
- Inorganic chemistry
دوره 52 15 شماره
صفحات -
تاریخ انتشار 2013